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Solubility and Solubility Product is considered one the most difficult concept.
33 Questions around this concept.
pH of a saturated solution of is 9. The solubility product of is:
The solubility of in water is at 298 K. The value of its solubility product (Ksp) will be
(Given molar mass of )
Using the Gibbs energy change, , for the following reaction,
The of in water at
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The pH of a saturated solution of is . The value of the solubility product of is :
Identify the correct order of solubility in aqueous medium:
Find out the solubility of in . Given that the ionic product of is .
The solubility of with solubility product in solution would be:
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and two nearly insoluble salts, have the same values of at room temperature. Which statement would be true in regard of and ?
Identify the correct order of solubility in aqueous medium:
In qualitative analysis, the metals of group I can be separated from other ions by precipitating them as chloride salts. A solution initially contains Ag+ and Pb2+ at a concentration is 0.10 M. Aqueous HCl is added to this solution until the Cl- concentration is 0.10 M. What will the concentrations of Ag+ and Pb2+ be at equilibrium?
$\left(\mathrm{K}_{\text {sp }}\right.$ for $\mathrm{AgCl}=1.8 \times 10^{-10}, \mathrm{~K}_{\text {sp }}$ for $\left.\mathrm{PbCl}_2=1.7 \times 10^{-5}\right)$
Solubility
It is the weight of solute present in 100 ml of solvent. It is denoted by 's' and is expressed in mol per litre or gm per litre. The number of moles of solute in 1 L of saturated solution is known as molar solubility.
Solubility decreases with the increase in concentration of common ion. It increases with temperature and increases in case the ions formed from the sparingly soluble salt undergo some sort of reaction like complexation.
Example, The solubility of AgCl in water in presence of AgNO3
Solubility increases due to complex ion formation. For example, AgCl has more solubility in ammonia due to complex formation
Solubility Product: It is the product of the molar concentrations of ions of an electrolyte in a saturated solution at a particular temperature. It is denoted by Ksp or S.
General Representation
Relation between Solubility(s) and Solubility Product (Ksp)
s 0 0
- xs ys
Solubility Product and Precipitation
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