Pearson | PTE
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Applications of Hyerconjugation - 1 is considered one of the most asked concept.
44 Questions around this concept.
How many tautomers can you draw for the following ketone?
Identify the compound that exhibits tautomerism.
Which of the following is a condition for tautomerism in nitrocompounds ?
Given:
Which of the given compounds can exhibit tautomerism ?
The enolic form of ethyl acetoacetate as below has:
In which of the following compounds, the C - CI bond ionisation shall give most stable carbonium ion ?
In which of the following compounds. the C-Cl bond ionisation shall give most stable carbonium ion?
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The product C is
Which one of the following substituents at para-position is most effective in stabilizing the phenoxide ion ?
Which one of the following is optically inactive?
Tautomers are isomers of a compound which differ only in the position of the protons and electrons. The carbon skeleton of the compound is unchanged. A reaction which involves simple proton transfer in an intramolecular fashion is called tautomerism.
The decreasing -I effect or increasing +I effect order is as follows:
–NH3+ > –NO2 > –SO2R > –CN > –SO3H > –CHO > –CO > –COOH > -F > –COCl > -CONH2 > –Cl > –Br > –I > –OR > -OH > -NR2 > –NH2 > –C6H5 > –CH=CH2 > –H
In hyperconjugation, more is the number of -carbons, more is the number of hyperconjugated structures and thus more is the stability. Thus, stability follows the given order:
3o carbocation > 2o carbocation > 1o carbocation
Try to solve the miscellaneous problems given in the video.
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