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Tautomerism MCQ - Practice Questions with Answers

Edited By admin | Updated on Sep 25, 2023 25:24 PM | #NEET

Quick Facts

  • Applications of Hyerconjugation - 1 is considered one of the most asked concept.

  • 38 Questions around this concept.

Solve by difficulty

Given:

Which of the given compounds can exhibit tautomerism ?

The enolic form of ethyl acetoacetate as below has:

In which of the following compounds, the C - CI bond ionisation shall give most stable carbonium ion ?

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 Which one of the following substituents at para-position  is  most effective  in stabilizing the phenoxide ion ?

Two possible stereo-structures of CH3CHOH.COOH, which are optically active, are called:

Which of the following compounds is not chiral?

Concepts Covered - 4

Question of Tautomerism

Tautomers are isomers of a compound which differ only in the position of the protons and electrons. The carbon skeleton of the compound is unchanged. A reaction which involves simple proton transfer in an intramolecular fashion is called tautomerism.

Application of Inductive Effect

The decreasing -I effect or increasing +I effect order is as follows:
–NH3+ > –NO2 > –SO2R > –CN > –SO3H > –CHO > –CO > –COOH > -F > –COCl > -CONH2 > –Cl > –Br > –I > –OR > -OH > -NR2 > –NH2 > –C6H5 > –CH=CH2 > –H

Applications of Hyerconjugation - 1

In hyperconjugation, more is the number of \alpha-carbons, more is the number of hyperconjugated structures and thus more is the stability. Thus, stability follows the given order:
3o carbocation > 2o carbocation > 1o carbocation

Mixed Questions - 1

Try to solve the miscellaneous problems given in the video.

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Question of Tautomerism
Application of Inductive Effect
Applications of Hyerconjugation - 1

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Books

Reference Books

Question of Tautomerism

Chemistry Part II Textbook for Class XI

Page No. : 348

Line : 18

Application of Inductive Effect

Chemistry Part II Textbook for Class XI

Page No. : 352

Line : 1

E-books & Sample Papers

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