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Entropy is considered one of the most asked concept.
10 Questions around this concept.
Which of the following is incorrect regarding the first law of thermodynamics?
The temperature- entropy diagram of a reversible engine cycle is given in the figure. Its efficiency is
Entropy- Entropy is a measure of the disorder of the molecular motion of a system. I.e Greater is the disorder, greater is the entropy.
The change in entropy is given as
The relation is called the mathematical form of the Second Law of Thermodynamics.
1. Entropy for solid and liquid-
i. When heat is given to a substance to change its state at a constant temperature.
Then change in entropy is given as
where positive sign refers to heat absorption and negative sign to heat evolution.
And and T is in kelvin.
ii. When heat is given to a substance to raises its temperature from
Then change in entropy is given as
where c = specific heat capacity
2. Entropy for an ideal gas -
For n mole of an ideal gas, the equation is given as PV = nRT
I.Entropy change for ideal gas in terms of T & V
From the first law of thermodynamics, we know that
and
using PV = nRT
II.Entropy change for an ideal gas in terms of T & P
III.Entropy change for an ideal gas in terms of P & V
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