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Mean Free Path MCQ - Practice Questions with Answers

Edited By admin | Updated on Sep 25, 2023 25:23 PM | #NEET

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25 \times 10^{-3}m^{3} volume cylinder is filled with 1 mol of O_{2} gas  at room temperature (300 K). The molecular diameter of O_{2}, and its root mean square speed are found to be 0.3 nm and 200 m/s respectively. What is the average collision rate (per second) for an O_{2} molecule?

The mean free path of molecules of a gas, (radius 'r') is inversely proportional to:

If the successive collision time interval of an ideal gas at a pressure of 2 atm and Temperature is 300 K is 6.0×10-8. What will be the new vision time if the pressure is doubled and the temperature is set to 500k?

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Consider an ideal gas continued in an isolated closed chamber. As the gas undergoes an adiabatic expansion, the average time of collision between molecules increases as V^q, Where V in the volume of the gas. The value of q is r=\frac{C_p}{C_v}

The mean free path of molecules of a gas (radius r) is inversely proportional to - 

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Mean free path

Mean Free Path - 

On the basis of kinetic theory of gases, it is assumed that the molecules of a gas are continuously colliding against each other. So, the distance travelled by a gas molecule between any two successive collisions is known as free path.

There are assumption for this theory that during two successive collisions, a molecule of a gas moves in a straight line with constant velocity. Now, let us discuss the formula of mean free path - 

                                                                          

Let  \lambda _1,\lambda _2.......\lambda_n be the distance travelled by a gas molecule during n collisions respectively, then the mean free path of a gas molecule is defined as - 

                       \lambda=\frac{\text { Total distance travelled by a gas molecule between successive collisions }}{\text { Total number of collisions }}

Here, \lambda is the mean free path.

It can also be written as -        \boldsymbol{\lambda=\frac{\lambda_{1}+\lambda_{2}+\lambda_{3}+\ldots+\lambda_{n}}{n}}

Now, let us take d = Diameter of the molecule,
                          N = Number of molecules per unit volume.

 

Also, we know that,  PV = nRT 

So, Number of moles per unit volume  =  \frac{n}{V }=\frac{P}{RT}

Also we know that number of molecules per unit mole  = N_A = 6.023 \times10^{23} 

So, the number of molecules in 'n' moles = nNA

So the number of molecules per unit volume is N =  \frac{PN_A}{RT}

                                                                 So, \dpi{100} \mathbf{\lambda = \frac{RT}{ \pi d^2PN_A}=\frac{kT}{\pi d^2P}}

If all the other molecules are not at rest then, \boldsymbol{\lambda=\frac{1}{\sqrt{2} \pi N d^{2}}}\mathbf{= \frac{RT}{\sqrt{2}\lambda d^2PN_A}=\frac{kT}{\sqrt{2}\pi d^2P}}

 

Now, if  \boldsymbol{\lambda=\frac{1}{\sqrt{2} \pi N d^{2}}}  and m = mass of each molecule then we can write - \lambda=\frac{1}{\sqrt{2} \pi N d^{2}}=\frac{m}{\sqrt{2} \pi(m N) d^{2}}=\frac{m}{\sqrt{2} \pi d^{2} \rho}

                                                                        So, \lambda \propto \frac{1}{\rho} \text { and } \lambda \propto m

 

                                         

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Mean free path

Physics Part II Textbook for Class XI

Page No. : 336

Line : 3

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