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Dinitrogen - Preparation, Properties And Uses MCQ - Practice Questions with Answers

Edited By admin | Updated on Sep 25, 2023 25:24 PM | #NEET

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Which of the following does not give oxygen on heating?

$Zn(ClO_3)_2$

$K_{2}Cr_{2}O_{7}$

$(NH_{4})_{2}Cr_{2}O_{7}$

$KClO_{3}$

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Which of the following is true regarding the reactivity of dinitrogen gas?

It is highly reactive and readily forms compounds with most elements.

It is relatively unreactive and does not readily form compounds with most elements.

It only reacts with metals to form nitrides.

It only reacts with halogens to form nitrogen halides.

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Concepts Covered - 0

Dinitrogen

Preparation
Dinitrogen is produced commercially by the liquefaction and fractional distillation of air. Liquid dinitrogen (b.p. 77.2 K) distils out first leaving behind liquid oxygen (b.p. 90 K). In the laboratory, dinitrogen is prepared by treating an aqueous solution of ammonium chloride with sodium nitrite.

$\mathrm{NH_{4}Cl(aq)\: +\: NaNO_{2}(aq)\: \rightarrow \: N_{2}(g)\: +\: 2H_{2}O(l)\: +\: NaCl(aq)}$

Small amounts of NO and HNO₃ are also formed in this reaction; these impurities can be removed by passing the gas through aqueous sulphuric acid containing potassium dichromate. It can also be obtained by the thermal decomposition of ammonium dichromate.

$\mathrm{(NH_{4})_{2}Cr_{2}O_{7}\: \overset{Heat}{\rightarrow}\: N_{2}\: +\: 4H_{2}O\: +\: Cr_{2}O_{3}}$

Very pure nitrogen can be obtained by the thermal decomposition of sodium or barium azide.

$\mathrm{Ba(N_{3})_{2}\: \rightarrow \: Ba\: +\: 3N_{2}}$

Properties
Dinitrogen is a colourless, odourless, tasteless and non-toxic gas. Nitrogen atom has two stable isotopes: ¹⁴N and ¹⁵N. It has a very low solubility in water (23.2 cm³ per litre of water at 273 K and 1 bar pressure) and low freezing and boiling points. Dinitrogen is rather inert at room temperature because of the high bond enthalpy of N≡N bond. Reactivity, however, increases rapidly with rise in temperature. At higher temperatures, it directly combines with some metals to form predominantly ionic nitrides and with non-metals, covalent nitrides. A few typical reactions are:

$\\\mathrm{6Li\: +\: N_{2}\: \overset{Heat}{\rightarrow}\: 2Li_{3}N}\\\\\mathrm{3Mg\: +\: N_{2}\: \overset{Heat}{\rightarrow}\: Mg_{3}N_{2}}$

Uses

The main use of dinitrogen is in the manufacture of ammonia and other industrial chemicals containing nitrogen, (e.g., calcium cyanamide).
It also finds use where an inert atmosphere is required (e.g., in iron and steel industry, inert diluent for reactive chemicals).
Liquid dinitrogen is used as a refrigerant to preserve biological materials, food items and in cryosurgery.