2 Questions around this concept.
In the laboratory, the heat released during combustion is measured in a bomb calorimeter.
It consists of an insulated vessel containing water and a rigid, constant volume container (called bomb) inside it.
The combustion process is carried out isochorically in the bomb and the heat released during combustion is trapped in the vessel and is used to raise the temperature of the calorimeter system.
The change in temperature can be measured with the help of thermometer and knowing the heat capacity of the system, the heat released due to combustion can be calculated.
Suppose T1 and T2 are initial and final temperatures and C be the heat capacity of the system, then
Now, since the combustion occurs in the rigid bomb, therefore the heat liberated is at constant volume and thus knowing the amount of substance undergoing combustion, the internal energy change during combustion can be calculated.
Once, the value of is calculated, we can calculate the
of the reaction using the following relation:
The pictorial representation of a calorimeter system is given below

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