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Electrophilic Substitution Reaction MCQ - Practice Questions with Answers

Edited By admin | Updated on Sep 25, 2023 25:24 PM | #NEET

Quick Facts

  • 22 Questions around this concept.

Solve by difficulty

The increasing order of the reactivity of the following compounds towards electrophilic aromatic substitution reactions is:

Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated HI?

What products are formed when the following compound is treated with Br2 in the presence of FeBr3?

Increasing order of the following for electrophilic substitution reaction as –

(I)

(II)

(III)

Concepts Covered - 2

Electrophilic substitution- 1
  • The ortho, para positions of phenols are electron-rich in nature.
  • Electrophile is electron deficient in nature. Thus, it tries to attack the position which is electron-rich.
  • Thus, compounds like phenols etc are called ortho-para directing.
  • The groups like Nitro-benzene are known as Meta-directing groups because they sent the electrophile to the meta position.
Electrophilic substitution- 2
  • -I effect only moves along sigma bond.
  • -M effect/resonance effect is always more prevalent than -I effect.
  • +M effect on the ring at 1 and 3 positions are equal in magnitude. But -I effect decreases as the distance increases.

Electrophile is electron deficient. Thus, it tries to go to the most electron-rich position.

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Electrophilic substitution- 1
Electrophilic substitution- 2

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Books

Reference Books

Electrophilic substitution- 1

Chemistry Part II Textbook for Class XI

Page No. : 400

Line : 30

Electrophilic substitution- 2

Chemistry Part II Textbook for Class XI

Page No. : 400

Line : 30

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